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Halite deposits have long been utilized for interrogating past climate conditions. Microthermometry on halite fluid inclusions has been used to determine ancient water temperatures. One notable obstacle in performing microthermometric measurements, however, is the lack of a vapor bubble in the single-phase liquid inclusions at room temperature. (Pseudo-) isochoric cooling of the inclusions to high negative pressures, far below the homogenization temperature, has commonly been needed to provoke spontaneous vapor bubble nucleation in the liquid. High internal tensile stress in soft host minerals like halite, however, may induce plastic deformation of the inclusion walls, resulting in a wide scatter of measured homogenization temperatures. Nucleation-assisted (NA) microthermometry, in contrast, employs single ultra-short laser pulses provided by a femtosecond laser to stimulate vapor bubble nucleation in metastable liquid inclusions slightly below the expected homogenization temperature. This technique allows for repeated vapor bubble nucleation in selected fluid inclusions without affecting the volumetric properties of the inclusions, and yields highly precise and accurate homogenization temperatures. In this study, we apply, for the first time, NA microthermometry to fluid inclusions in halite and we evaluatethe precision and accuracy of this thermometer utilizing (i) synthetic halite crystals precipitated under controlled laboratory conditions, (ii) modern natural halite that precipitated in the 1980s in the Dead Sea, and (iii) Late Pleistocene halite samples from a sediment core from Death Valley, CA. Our results demonstrate an unprecedented accuracy and precision of the method that provides a new opportunity to reconstruct reliable quantitative temperature records from evaporite archives. 

Abstract The growth and decay of the Laurentide ice sheet altered the hydrological cycle over southwestern North America. While it is well‐documented that the last glacial was wetter and had isotopically lighter precipitation, much less information is available for prior glacials. Increased proxy coverage is needed to test climate models' ability to reconstruct these changes and to assess their predictive power for water availability in response to future climate change. Here, we present parallel precipitation isotope records spanning the last two glacial cycles from two large, proximal lakes in Utah, USA: Great Salt Lake and Bear Lake. We use plant waxn‐alkane δD as a proxy for precipitation δD (δD_precip) and find coherent glacial‐interglacial fluctuations in δD_precip, with a ∼30‰ D‐depletion during glacial maxima relative to interglacials. We find similar δD_precipvalues between the Holocene and Eemian, but at the lower‐pCO₂MIS 7 interglacial, D‐enrichment is only weakly recorded at Great Salt Lake and absent at higher elevation Bear Lake. Comparison to regional proxy archives finds large‐scale coherence in regional hydroclimate change over the last two glacial cycles is best explained by thermodynamic processes, with increased rainout efficiency, isotopic fractionation, and snow in a colder atmosphere. Comparison of proxies to climate model experiments showed models considerably underestimate glacial lowering of precipitation isotopic values, but overestimate inland Rayleigh distillation. New and assembled proxy reconstructions provide greater temporal and spatial coverage as targets for model skill in capturing hydroclimate variations across the past two glacial cycles. 

Lacustrine halite deposits have long been utilized for interrogating past climate conditions. In particular, microthermometry performed on fluid inclusions in halite crystals has been used to interpret lake water temperatures from ancient deposits. One notable obstacle in performing microthermometry in halite fluid inclusions is the lack of a vapour bubble in the single-phase liquid brine. Isochoric cooling of the inclusions to high negative pressures far below the homogenization temperature has commonly been used to provoke spontaneous vapor bubble nucleation in the metastable liquid. In a host minerals like halite, however, internal tensile stress may result in plastic deformation of the inclusion walls and typically a wide scatter of measured homogenization temperatures. Nucleation-assisted microthermometry, in contrast, employs single ultra-short laser pulses provided by a femtosecond laser to stimulate vapour bubble nucleation in metastable single-phase liquid inclusions slightly below the expected homogenization temperature. This technique allows for repeated vapour bubble nucleation in fluid inclusions without damaging the inclusion walls, yielding highly precise and accurate paleotemperatures from halite fluid inclusions. Moreover, the highly selective nature of nucleation-assisted microthermometry allows for a higher degree of quality control compared to the previous standard method. In this study, we tested the precision and accuracy of nucleation-assisted microthermometry for use in paleoclimate reconstruction utilizing modern halites precipitated in the laboratory under controlled and monitored conditions, Pleistocene halite samples from Death Valley, and varved halites precipitated in the 1980s in the Dead Sea. 

Abstract Ancient lake deposits in the Mojave Desert indicate that the water cycle in this currently dry place was radically different under past climates. Here we revisit a 700 m core drilled 55 years ago from Searles Valley, California, that recovered evidence for a lacustrine phase during the late Pliocene. We update the paleomagnetic age model and extract new biomarker evidence for climatic conditions from lacustrine deposits (3.373–2.706 Ma). The MBT′_5Metemperature proxy detects present‐day conditions (21 ± 3°C,n = 2) initially, followed by warmer‐than‐present conditions (25 ± 3°C,n = 17) starting at 3.268 and ending at 2.734 Ma. Bacterial and archeal biomarkers reveal lake salinity increased after 3.268 Ma likely reflecting increased evaporation in response to higher temperatures. The δ¹³C values of plant waxes (−30.7 ± 1.4‰,n = 28) are consistent with local C₃taxa, likely expanded conifer woodlands during the pluvial with less C₄than the Pleistocene. δD values (−174 ± 5‰,n = 25) of plant waxes indicate precipitation δD values (−89 ± 5‰,n = 25) in the late Pliocene are within the same range as the late Pleistocene precipitation δD. Microbial biomarkers identify a deep, freshwater lake and a cooling that corresponds to the onset of major Northern Hemisphere glaciation at marine isotope stage marine isotope stages M2 (3.3 Ma). A more saline lake persisted for ∼0.6 Ma across the subsequent warmth of the late Pliocene (3.268–2.734 Ma) before the lake desiccated at the Pleistocene intensification of Northern Hemisphere Glaciation. 

Femtosecond lasers, fired in short pulses, can induce bubble cavitation in single-phase liquid fluid inclusions at temperatures near the inclusion homogenization temperature. By coupling femtosecond laser-induced cavitation with microthermometry, paleotemperatures can be extracted from fluid inclusions in primary halite crystals. This technique minimizes plastic deformation of halite by not subjecting samples to extreme temperatures during vapor bubble nucleation. The resultant homogenization temperatures are precise and reproducible. We applied this technique to Eocene Green River Formation primary bottom-growth halites from the Piceance Creek Basin in Colorado. Samples from the basin-center Savage 24-1 core yield average bottom water temperatures of 27.0 ± 1.3 ºC and 20.1 ± 1.2 ºC for the Upper and Lower Salt intervals, respectively. Average bottom water temperatures from modern perennial hypersaline lakes have been shown to reflect the local mean annual air temperature. Therefore, homogenization temperatures from primary bottom-growth halite fluid inclusions are a proxy for mean annual air temperature. These results agree with regional Early Eocene mean annual air temperature estimate ranges from other mineralogical and biochemical proxies, bolstering the reliability of temperature estimates obtained using this technique. Additionally, the highly selective nature of laser induced cavitation microthermometry allows for a higher degree of quality control compared to standard microthermometry, yielding more reproducible and precise results. 

Lacustrine strata are often among the highest-resolution terrestrial paleoclimate archives available. The manner in which climate signals are registered into lacustrine deposits varies, however, as a function of complex sedimentologic and diagenetic processes. The retrieval of reliable records of climatic forcing therefore requires a means of evaluating the potential influence of changing sedimentary transfer functions. Here, we use high-resolution X-ray fluorescence core scanning of the Wilkins Peak Member of the Green River Formation to characterize the long-term evolution of transfer functions in an ancient lacustrine record. Our analysis identifies a shift in the frequency distribution of Milankovitch-band variance between the lower and middle Wilkins Peak Member across a range of temporally calibrated elemental intensity records. Spectral analysis of the lower Wilkins Peak Member shows strong short eccentricity, obliquity, precession, and sub-Milankovitch−scale variability, while the middle Wilkins Peak Member shows strong eccentricity variability and reduced power at higher frequencies. This transition coincides with a dramatic decline in the number and volume of evaporite beds. We attribute this shift to a change in the Wilkins Peak Member depositional transfer function caused by evolving basin morphology, which directly influenced the preservation of bedded evaporite as the paleolake developed from a deeper, meromictic lake to a shallower, holomictic lake. The loss of bedded evaporite, combined with secondary evaporite growth, results in reduced obliquity- and precession-band power and enhanced eccentricity-band power in the stratigraphic record. These results underscore the need for careful integration of basin and depositional system history with cyclostratigraphic interpretation of the dominant astronomical signals preserved in the stratigraphic archive. 

Abstract Great Salt Lake, Utah, is a hypersaline terminal lake in the Great Basin, and the remnant of the late glacial Lake Bonneville. Holocene hydroclimate variations cannot be interpreted from the shoreline record, but instead can be investigated by proxies archived in the sediments. GLAD1-GSL00-1B was cored in 2000 and recently dated by radiocarbon for the Holocene section with the top 11 m representing ∼7 ka to present. Sediment samples every 30 cm (∼220 years) were studied for the full suite of microbial membrane lipids, including those responsive to temperature and salinity. The Archaeol and Caldarchaeol Ecometric (ACE) index detects the increase in lipids of halophilic archaea, relative to generalists, as salinity increases. We find Holocene ACE values ranged from 81-98, which suggests persistent hypersalinity with <50 g/L variability across 7.2 ka. The temperature proxy, MBTʹ5Me, yields values similar to modern mean annual air temperature for months above freezing (MAF = 15.7°C) over the last 5.5 ka. Several GDGT metrics show a step shift in microbial communities and limnology at 5.5 ka. Extended archaeol detects elevated salinity during the regional mid-Holocene drought, not readily detected in the ACE record that is often near the upper limit of the index. We infer that the mid-Holocene GSL was shallower and saltier than the late Holocene. The current drying may be returning the lake to conditions not seen since the mid-Holocene. Plain Language Summary Great Salt Lake in Utah is the remnant of a once much larger lake and is currently at a historically low level. We study a lake sediment core, collected in 2000 from the floor of Great Salt Lake, and recently dated. We take new samples from the core and measure them for molecules made by microbes, whether living in the lake or washed in from the surrounding soils. We reconstruct lake conditions during the last 7,200 years and assess whether lake level fluctuated during that time. Over the past 7,200 years, we find evidence that the lake was shallower from 7,200 to 5,500 years ago but has been relatively stable until the modifications of the lake in the 20th century and the current drying trend. 

Lacustrine chemical sediments of the Wilkins Peak Member, Eocene Green River Formation potentially preserve paleoclimate information relating to the conditions of their formation and preservation within the lake basin during the Early Eocene Climatic Optimum. The Green River Formation comprises the world’s largest sodium-carbonate evaporite deposit in the form of trona (Na2CO3⋅NaHCO3⋅2H2O) in the Bridger sub-basin and nahcolite (NaHCO3) in the neighboring Piceance Creek basin. Modern analogues suggest that these minerals necessitate the existence of an alkaline source water. Detrital provenance geochronometers suggest that the most likely source for volcanic waters to the Greater Green River Basin is the Colorado Mineral Belt, connected to the basin via the Aspen paleo-river. We tested the hypothesis that magmatic waters from the Colorado Mineral Belt could have supplied the Greater Green River Basin with the alkalinity needed to precipitate sodium-carbonate evaporites that are preserved in the Wilkins Peak Member by numerically simulating the evaporation of modern soda spring waters from northwestern Colorado at various temperature and atmospheric pCO2 conditions. We compare the resulting simulated evaporite sequences of the modern soda spring waters to the mineralogy preserved within the Wilkins Peak Member. Simulated evaporation of Steamboat Springs water produces the closest match to core observations and mineralogy. These simulations provide constraints on the salinities at which various minerals precipitated in the Wilkins Peak Member as well as insights into the regional temperature (>15ºC for gaylussite and trona; >27º for pirssonite and trona) and pCO2 conditions (<1200ppm for gaylussite and trona) during the EECO.